ANALISIS KANDUNGAN LOGAM BERAT PB DAN SIFAT KIMIA TANAH PADA LAHAN HORTIKULTURA
Keywords:
Hortikultura, Logam berat Pb, Pupuk fosfatAbstract
Penelitian ini dilakukan untuk mengetahui konsentrasi logam berat Pb di kebun hortikultura Kelurahan Rewarangga Selatan. Kontaminasi logam berat Pb diakibatkan oleh penggunaan pupuk fosfat secara terus menerus dan juga logam berat Pb berasal dari limbah domestik yang masuk melalui air irigasi. Logam berat Pb diekstraksi menggunakan metode destruksi basa dan hasil analisis dengan spektrofotometer serapan atom menunjukan konsentrasi Pb sebesar 52 ppm. Hasil analisi sifat kimia tanah menujukkan pH tanah bersifat netral dengan nilai pH 6,2-6,8. Nilai kapasitas tukar kation cukup tinggi yaitu sebesar 65,6 Meq/100g yang menunjukkan tingkat kesuburan tanah yang masih bagus. C-Organik juga menunjukan nilai yang tinggi yaitu sebesar 3,67 %. Hal ini mengindikasikan banyaknya senyawa organik seperti asam humat dan asam fulfat yang dapat membentuk senyawa kompleks dengan logam berat Pb. Dari hasil analisis sifat kimia tanah diprediksikan bahwa logam berat Pb sulit teradsorpsi oleh tanaman, karena kondisi lingkungan yang tidak memungkinkan logam berat Pb berada dalam bentuk ion Pb2+ yang mudah diserap oleh tanaman.
References
Aide, M., & Braden, I. (2018). Lead Sequestration in the Soil Environment with an Emphasis on the Chemical Thermodynamics Involving Phosphate as a Soil Amendment: Review and Simulations. International Journal of Applied Agricultural Research, 13(1), 9–19.
Alloway, B. J. (2009). Soil factors associated with zinc deficiency in crops and humans. Environmental Geochemistry and Health, 31(5), 537–548. https://doi.org/10.1007/s10653-009-9255-4
Ananda Alfan, M., Bieby Voijant, T., Anak Agung, G. K., & Kriyo, S. (2019). Study of Lead (Pb) Distribution in Soil of Jetis District, Mojokerto Regency. Journal of Civil Engineering and Environmental Sciences, 5(2), 005–012. https://doi.org/10.17352/2455-488x.000032
Cai, L. M., Xu, Z. C., Qi, J. Y., Feng, Z. Z., & Xiang, T. S. (2015). Assessment of exposure to heavy metals and health risks among residents near Tonglushan mine in Hubei, China. Chemosphere, 127, 127–135. https://doi.org/10.1016/j.chemosphere.2015.01.027
Chen, C., Tian, T., Wang, M. K., & Wang, G. (2016). Release of Pb in soils washed with various extractants. Geoderma, 275, 74–81. https://doi.org/10.1016/j.geoderma.2016.04.015
Darma, S., Ramayana, S., & Suprianto, B. (n.d.). Comparison of Content and Status of the C-Organic , Nitrogen , C / N Ratio , Soil pH , and Organic Matter in Rainfed , Tidal and Swampy Rice Fields ( Case Study in Three Villages , in East Kalimantan ).
Delil, A. D., & Köleli, N. (2019). Investigation of a combined continuous flow system for the removal of Pb and Cd from heavily contaminated soil. Chemosphere, 229, 181–187. https://doi.org/10.1016/j.chemosphere.2019.04.201
Easley, R. A., & Byrne, R. H. (2011). The ionic strength dependence of lead (II) carbonate complexation in perchlorate media. Geochimica et Cosmochimica Acta, 75(19), 5638–5647. https://doi.org/10.1016/j.gca.2011.07.007
El-Taher, A., & Althoyaib, S. S. (2012). Natural radioactivity levels and heavy metals in chemical and organic fertilizers used in Kingdom of Saudi Arabia. Applied Radiation and Isotopes, 70(1), 290–295. https://doi.org/10.1016/j.apradiso.2011.08.010
Fahr, M., Laplaze, L., Bendaou, N., Hocher, V., El Mzibri, M., Bogusz, D., & Smouni, A. (2013). Effect of lead on root growth. Frontiers in Plant Science, 4(JUN), 1–7. https://doi.org/10.3389/fpls.2013.00175
Feng, C., Chen, Y., Zhang, S., Wang, G., Zhong, Q., Zhou, W., Xu, X., & Li, T. (2020). Removal of lead, zinc and cadmium from contaminated soils with two plant extracts: Mechanism and potential risks. Ecotoxicology and Environmental Safety, 187(May 2019). https://doi.org/10.1016/j.ecoenv.2019.109829
Gondar, D., López, R., Fiol, S., Antelo, J. M., & Arce, F. (2006). Cadmium, lead, and copper binding to humic acid and fulvic acid extracted from an ombrotrophic peat bog. Geoderma, 135, 196–203. https://doi.org/10.1016/j.geoderma.2005.12.003
Haque, E., Thorne, P. S., Nghiem, A. A., Yip, C. S., & Bostick, B. C. (2021). Lead (Pb) concentrations and speciation in residential soils from an urban community impacted by multiple legacy sources. Journal of Hazardous Materials, 416(February), 125886. https://doi.org/10.1016/j.jhazmat.2021.125886
Jaishankar, M., Tseten, T., Anbalagan, N., Mathew, B. B., & Beeregowda, K. N. (2014). Toxicity, mechanism and health effects of some heavy metals. Interdisciplinary Toxicology, 7(2), 60–72. https://doi.org/10.2478/intox-2014-0009
Jiao, W., Chen, W., Chang, A. C., & Page, A. L. (2012). Environmental risks of trace elements associated with long-term phosphate fertilizers applications: A review. Environmental Pollution, 168, 44–53. https://doi.org/10.1016/j.envpol.2012.03.052
Koralegedara, N. H., Al-Abed, S. R., Rodrigo, S. K., Karna, R. R., Scheckel, K. G., & Dionysiou, D. D. (2017). Alterations of lead speciation by sulfate from addition of flue gas desulfurization gypsum (FGDG) in two contaminated soils. Science of the Total Environment, 575, 1522–1529. https://doi.org/10.1016/j.scitotenv.2016.10.027
Landrot, G., & Khaokaew, S. (2018). Lead Speciation and Association with Organic Matter in Various Particle-Size Fractions of Contaminated Soils. Environmental Science and Technology, 52(12), 6780–6788. https://doi.org/10.1021/acs.est.8b00004
Leštan, D., Gr?man, H., Zupan, M., & Ba?ac, N. (2003). Relationship of soil properties to fractionation of Pb and Zn in soil and their uptake into Plantago lanceolata. Soil and Sediment Contamination, 12(4), 507–522. https://doi.org/10.1080/713610986
Liu, L., Li, W., Song, W., & Guo, M. (2018). Remediation techniques for heavy metal-contaminated soils: Principles and applicability. Science of the Total Environment, 633, 206–219. https://doi.org/10.1016/j.scitotenv.2018.03.161
Milinovic, J., Lukic, V., Nikolic-Mandic, S., & Stojanovic, D. (2008). Concentrations of heavy metals in NPK fertilizers imported in Serbia. Pesticidi i Fitomedicina, 23(3), 195–200. https://doi.org/10.2298/pif0803195m
Violante, A., Cozzolino, V., Perelomov, L., Caporale, A. G., & Pigna, M. (2010). Mobility and bioavailability of heavy metals and metalloids in soil environments. Journal of Soil Science and Plant Nutrition, 10(3), 268–292. https://doi.org/10.4067/S0718-95162010000100005
Xu, Q., Duan, D., Cai, Q., & Shi, J. (2018). Influence of Humic Acid on Pb Uptake and Accumulation in Tea Plants. Journal of Agricultural and Food Chemistry, 66(46), 12327–12334. https://doi.org/10.1021/acs.jafc.8b03556.


